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The Relationships between Kaolinite Crystal Properties and the Origin of Materials for a Brazilian Kaolin Deposit
- Angélica F. Drummond C. Varajāo, Robert J. Gilkes, Robert D. Hart
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- Journal:
- Clays and Clay Minerals / Volume 49 / Issue 1 / February 2001
- Published online by Cambridge University Press:
- 28 February 2024, pp. 44-59
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The clay particles in a kaolin deposit from Brazil were investigated by X-ray diffraction (XRD), differential thermal analysis (DTA), analytical transmission electron microscopy (ATEM), and electron paramagnetic resonance (EPR) to examine the relationships between morphological and chemical properties of the crystals and to relate these properties to formation conditions. The XRD patterns show the dominant presence of kaolinite with minor amounts of gibbsite, illite, quartz, goethite, hematite, and anatase. ATEM observations show two discontinuities in the deposit as indicated by changes in morphology and size of the kaolinite crystals. At the base of the deposit, hexagonal platy and lath-shaped particles (mean area of 001 face = 0.26 μm2) maintain the original fabric of the parent rock which characterizes an in situ evolution. In the middle of the deposit a bimodal population of large (mean area of 001 face > 0.05 μm2) and small (mean area of 001 face < 0.05 μm2) sub-hexagonal platy kaolinite crystals occurs. This zone defines the boundary between the saprolitic kaolinite and the pedogenic kaolinite. Near the top of the profile, laths and irregular plates of kaolinite, together with sub-hexagonal particles, define two different depositional sources in the history of formation of the deposit. Crystal thickness as derived from the width of basal reflections and the Hinckley index are compatible with the morphological results, but show only one discontinuity. At the base of the deposit, kaolinite has a low- defect density whereas in the middle and at the top of the profile, kaolinite has a high-defect density. Likewise, EPR spectroscopy shows typical spectra of low-defect kaolinite for the bottom of the deposit and typical spectra of high-defect kaolinite for the other portions of the deposit. Despite the morphological changes observed through the profile, the elemental composition of individual kaolinite crystals did not show systematic variations. These results are consistent with the deposit consisting of a transported pedogenic kaolinite over saprolite consisting of in situ kaolinized phyllite.
Structural features and formation conditions of mud diapirs in the Andaman Sea Basin
- WENGANG HE, JIANXUN ZHOU
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- Journal:
- Geological Magazine / Volume 156 / Issue 4 / April 2019
- Published online by Cambridge University Press:
- 06 March 2018, pp. 659-668
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Data from offshore oil and gas explorations have revealed that mud diapirs occur widely not only at continental margins but also in foreland basins and may have played an important role in the entrapment of oil and gas. Although the structural features and formation mechanism of salt diapirs have been extensively investigated, mud diapirs are still not fully understood, largely due to the difficulty of identifying them from seismic data. In this paper, the structural features and main controlling factors of mud diapirs in the Andaman Sea Basin are investigated based on seismic profiles combined with drilling data and regional tectonic settings. The results show that there are five types of mud diapir in the Andaman Sea Basin: turtleback mud diapir, mud dome, piercing mud diapir, mud volcano and gas chimney-like mud diapir. Turtleback mud diapirs mainly occur in the southern segment of the accretionary wedge of the Andaman Sea Basin, which is far from the Bengal Fan and characterized by low deposition rate and strong compression tectonic setting. Piercing mud diapirs exist mainly in the central segment of the accretionary wedge, which is close to provenances of sediments and characterized by rapid sedimentation rates, large mudstone thickness and transpressional tectonic setting. Mud domes and mud volcanoes mainly occur in the northern segment of the accretionary wedge, which is characterized by rapid sedimentation rates, large mudstone thickness and sedimentary wedge growth tectonic setting. The gas chimney-like mud diapirs only occur in the northern segment of the back-arc depression close to the Sagaing strike-slip fault belt, which is characterized by high deposition rate, large mudstone thickness and high geothermal gradient. These features suggest that thick mudstone deposit, rapid sedimentation rates, large geothermal gradient, strong tectonic stress and gravitational spreading and sliding may have prompted the formation of mud diapirs in the Andaman Sea Basin.